How to open a program on particular desktop?

Solution 1:

try devilspie:

Devil's Pie can be configured to detect windows as they are created, and match the window to a set of rules. If the window matches the rules, it can perform a series of actions on that window. For example, I can make all windows created by X-Chat appear on all workspaces, and the main Gkrellm1 window does not appear in the pager or task list.