Solution 1:

If $(X,Y)$ are jointly Gaussian with mean zero, then $P(X>0,Y>0)={\arccos(-\rho)\over 2\pi}$ where $\rho$ is the correlation of $X$ and $Y$.

Therefore, for Brownian motion and $0<s<t$ $$P(B_s>0, B_t>0)={\arccos(-\sqrt{s/t})\over 2\pi}.$$