Why use "his" in association with the word "mankind"?
Solution 1:
The use of 'his' refers to each 'member' of mankind. Mankind is generally referred to in this way, i.e. as a group of individual people, as opposed to a single, monolithic body, which would be suggested by using 'its'.
Solution 2:
"his" (male pronoun) emphasises that it's a human.
"its" (neuter pronoun) would suggest a less human thing or entity.
Compare:
Jeremy the baker got used to his surroundings
and
Fido the dog got used to its surroundings
Solution 3:
This is an old conundrum. English has no proper neutral pronoun to either a male or female person. It is usually used to refer to inanimate or not-human things.
You could say:
The power to become habituated to one's surroundings is a marked characteristic of mankind.
But the usage of one as a pronoun has come to sound a bit pretentious. I believe there is a shift occurring in english where their is being used in the singular and becoming acceptable.
The power to become habituated to their surroundings is a marked characteristic of mankind.
Some would take it a step further.
The power to become habituated to their surroundings is a marked characteristic of humans.
But that's somehow less poetic. Humans seems more clinical, and mankind more familial and grandiose somehow.