Why is the Plancherel measure interesting?
One can average a class function $f:G\to\Bbb C$ for a finite group $G$ by interpreting $f$ as a complex-valued function on the space ${\rm cl}(G)$ of conjugacy classes and computing the expectation $\Bbb E(f(C))$, where $C$ is a class-valued random variable whose distribution is pulled from the uniform one on $G$.
In light of $\sum(\dim\rho)^2=|G|$ (where the sum is over complex irreps $\rho$), we could equally attach the weights $(\dim\rho)^2/|G|$ to irreps and turn $\widehat{G}$ into a probability space. This is how we get the Plancherel measure on a finite group. But what question is the Plancherel measure an answer to? Historically, we know the Lebesgue and more generally the Haar measure answer the question of translation-invariant measures, and do so nicely (existence and uniqueness). Is there some a priori system of nice properties we might have liked a measure on irreps to have, which we could have later discovered the Plancherel measure uniquely satisfies?
For $G$ locally compact abelian, the complex irreps comprising $\widehat{G}$ are $1$-dimensional and form a group under tensoring - this is just the dual group, which has its own topology (the compact-open topology), and the Plancherel measure is just the Haar measure. However if $G$ is nonabelian, the irreps can be higher-dimensional and so aren't closed under tensor product. (Pontryagin duality generalizes to Tannaka-Krein duality, where we look at symmetry of the tensor operation on the full category of reps to recover $G$, at least as I understand it.) I may be muddying the waters with infinite nonabelian $G$ though, as I don't know how to define the Plancherel measure in that context.
We know conjugacy classes are dual to irreducible representations (see Qiaochu's answer here; the tl;dr version is that they are identified with the maxspecs of two algebras in a dual pairing). They are not generally in bijection, but one situation where they are in bijection is with finite symmetric groups. There might be some process that is "dual" to averaging class functions (which is where the boring measure on the set of conjugacy classes appears) in which the Plancherel measure is useful. This could also potentially explain why there are applications of the Plancherel measure on symmetric groups to combinatorial/probabilistic questions but I haven't seen any applications with other groups.
What you ultimately want to study is (upon fixing a Haar measure in the noncompact case) the left regular representation $\lambda\colon G\to U(L^2(G,\mathrm{Haar}))$. Now, general theory tells us that while it's not always possible to decompose $L^2(G)$ as a direct sum of irreducible reprenentations (this already fails for $G=\mathbb Z$), it is always possible to decompose it as a direct integral of irreducible representations (which are parametrised by the unitary dual $\widehat G$ of $G$). Now, if $G$ is unimodular and type I, the direct integral decomposition (with respect to both left and right actions of $G$) is as follows: $$ L^2(G) \cong \int_{\widehat G} H_\pi\,d\mu(\pi), $$ where $H_\pi = \pi\otimes \pi^*$, and its understanding requires, in particular, to determine the measure $\mu$ on $\widehat G$ such that the above becomes an isometric isomorphism. The unique measure with this property is called the Plancherel measure of $G$ (associated to a given Haar measure). Equivalently, it's the unique measure such that $$ \|f\|_2^2 = \int_{\widehat{G}} \|\pi(f)\|_{\mathrm{HS}}^2 \mathrm{d}\mu(\pi),\quad f\in L^1(G,\mathrm{Haar})\cap L^2(G,\mathrm{Haar}). $$