How to remap a single specific Key to a Windows Shorcut?

Solution 1:

This is easily accomplished with AutoHotKey.

AutoHotkey is a free, open-source macro-creation and automation software utility that allows users to automate repetitive tasks in Microsoft Windows. Any application user interface can be modified by AutoHotkey (for example, overriding the default Windows control key commands with their Emacs equivalents). It is driven by a custom scripting language that is aimed specifically at providing keyboard shortcuts or hotkeys.

The script would be:

pause::run "full path of your shortcut"

Obviously, put the path to your shortcut in the quotes.

There are other methods to sleep, shutdown, hibernate, or restart your PC. You can find the commands here. Read through the comments though on the selected answer, there are some caveats that can be worked around.

Personally, I love AutoHotKey. I remap the media keys on my keyboard (I never use them for media) to do things like open a command prompt, start a remote desktop session, open Notepad++, start the snipping tool, etc.