Describing disdain on someone's face
He turned to her with a contemptuous face...
Contemptuous means
expressing contempt:
- a contemptuous manner/laugh (Cambridge)
WordHippo has plenty of synonyms so you can choose.
It is not the most common of expressions, as it is formal, but it is used in literary works:
"Oh , it's worse than foolish ; it's downright sneaking , you know," replied Lowten , nibbing the pen with a contemptuous face. (The Posthumous Papers of the Pickwick, Charles Dickens)
GNgram shows that its use is increasing.