Proof of $n^2 \leq 2^n$.
Solution 1:
First since one must have $n\neq 3$, the induction base must be $n=4$. For the induction step: Suppose $n^2\le 2^n$. Then, $$(n+1)^2=n^2+2n+1\le 2^n+2n+1\le 2^n+2^n=2^{n+1}$$ because $2n+1\le 2^n$ for $n\ge 3$ (why is this true?).
If you had started with inductive base $0,1$ or $2$, then you would have ran into problems because $2n+1\le 2^n$ doesn't hold for $n=2$
Proof of $2n+1\le 2^n$ for $n\ge 3$.
Induction base: For n=3, $$2\cdot 3+1=7\le 8=2^3$$ Induction step: Assume that for $n\ge 3$, $2n+1\le 2^n$. Then $$2(n+1)+1=2n+1+2\le 2^n+2\le 2^n+2^n=2^{n+1}$$ and so we are done
Solution 2:
An analysis type proof.
$x^{1/x}$ has its maximum at $x = e$ and is increasing for $1 < x < e$ and decreasing for $x > e$.
$2^{1/2} = 4^{1/4}$, so $x^{1/x} < 2^{1/2}$ for $x > 4$ or $x^2 < 2^x$ for $x > 4$.
I am surprised that this worked out so nicely.
Obvious generalization: If $x > e$ and $y$ satisfies $1 < y < e$ and $y^{1/y} = x^{1/x}$ then $z^{1/z} < y^{1/y}$ for $z > x$ or $z^y < y^z$ for $z > x$.
Solution 3:
Another possibility is to write $$2^n = \sum\limits_{k=0}^n C_n^k \geq 1+n+ \frac{n(n-1)}{2} + \frac{n(n-1)(n-2)}{6} \geq n^2$$ for $n \geq 5$. It can be interpreted as follow: the set $\{1,...,n\}$ has at least $n^2$ subsets of cardinality at most three, and exactly $2^n$ subsets; therefore, $2^n \geq n^2$.