Derivative and constant function
Solution 1:
There is an everywhere differentiable non-constant function such that the set $Z=\{x: f'(x) = 0 \}$ is dense. The following paper gives an example of such a function:
Y. Katznelson and Karl Stromberg. Everywhere Differentiable, Nowhere Monotone, Functions. The American Mathematical Monthly , vol. 81, no. 4 (Apr., 1974), pp. 349-354.
According to this paper:
Examples of such functions are seldom given, or even mentioned, in books on real analysis. The first explicit construction of such a function was given by Kopcke (1889). An example due to Pereno (1897) is reproduced in [1], pp. 412-421.
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[1] E. W. Hobson, Theory of Functions of a Real Variable II, Dover, New York, 1957
Solution 2:
No you can't (but I don't have the example).
Look at this answer, where it is stated that the set of discontinuities of a derivative can be dense and have several other properties.