Could we turn on word wrap Safari Web Inspector?

Word wrap works a little differently, but actually more accurate, in the latest versions of Safari, depending on the mode you're displaying.

For instance, in the "Elements" tab, it will wrap as desired:

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But, like in your screenshot, the "Resources" tab for instance, it will display as the rendering engine intended, unwrapped:

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Click on the settings cog-wheel to the far right of the tabs and check the box that reads "Wrap lines to editor width". Resources will now be wrapped.