How to list all untagged files in Mavericks Finder?

Solution 1:

Ok, I should have taken a look at SuperUser, here's a way to do what AllInOne says without fiddling with XML files (and it's faster).
Simply create a new smart folder or hit cmd+F, choose "Raw Query" from the filters and type kMDItemUserTags != '*' in the field.

Solution 2:

A simple way to do this in Finder...

At the top of the finder window you see the column headers such as "Name", "Size", "Kind" etc like in the picture below.

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Just right click on any column header and you can add a column called "tags"as seen here.

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Then you can sort that column.