Read XML Attribute using XmlDocument

XmlNodeList elemList = doc.GetElementsByTagName(...);
for (int i = 0; i < elemList.Count; i++)
{
    string attrVal = elemList[i].Attributes["SuperString"].Value;
}

You should look into XPath. Once you start using it, you'll find its a lot more efficient and easier to code than iterating through lists. It also lets you directly get the things you want.

Then the code would be something similar to

string attrVal = doc.SelectSingleNode("/MyConfiguration/@SuperNumber").Value;

Note that XPath 3.0 became a W3C Recommendation on April 8, 2014.

You can migrate to XDocument instead of XmlDocument and then use Linq if you prefer that syntax. Something like:

var q = (from myConfig in xDoc.Elements("MyConfiguration")
         select myConfig.Attribute("SuperString").Value)
         .First();

I have an Xml File books.xml

<ParameterDBConfig>
    <ID Definition="1" />
</ParameterDBConfig>

Program:

XmlDocument doc = new XmlDocument();
doc.Load("D:/siva/books.xml");
XmlNodeList elemList = doc.GetElementsByTagName("ID");     
for (int i = 0; i < elemList.Count; i++)     
{
    string attrVal = elemList[i].Attributes["Definition"].Value;
}

Now, attrVal has the value of ID.