Splitting emails for a single domain into two

You can use transport maps

transport_maps = hash:/etc/postfix/transport

/etc/postfix/transport
[email protected] smtp:[remote.postfix.ip.address]
[email protected] smtp:[remote.postfix.ip.address]
[email protected] smtp:[remote.postfix.ip.address]
...
[email protected] smtp:[remote.postfix.ip.address]

Don't forget to create map file and restart the postfix

# postmap /etc/postfix/transport
# service postfix restart