How to read HTML as XML?

HTML simply isn’t the same as XML (unless the HTML actually happens to be conforming XHTML or HTML5 in XML mode). The best way is to use a HTML parser to read the HTML. Afterwards you may transform it to Linq to XML – or process it directly.

I haven't used it myself, but I suggest you take a look at SGMLReader. Here's a sample from their home page:

XmlDocument FromHtml(TextReader reader) {

    // setup SgmlReader
    Sgml.SgmlReader sgmlReader = new Sgml.SgmlReader();
    sgmlReader.DocType = "HTML";
    sgmlReader.WhitespaceHandling = WhitespaceHandling.All;
    sgmlReader.CaseFolding = Sgml.CaseFolding.ToLower;
    sgmlReader.InputStream = reader;

    // create document
    XmlDocument doc = new XmlDocument();
    doc.PreserveWhitespace = true;
    doc.XmlResolver = null;
    doc.Load(sgmlReader);
    return doc;
}