locally isometric is not a symmetric relation.
Solution 1:
This depends on the precise definition of the relation "$M$ and $N$ are locally isometric". For the first two definitions that sprang to my mind, the answer is "no."
If one defines "$M$ and $N$ are locally isometric if there exists a local isometry $f:M\to N$", then the relation is not symmetric. Consider, say, a closed complete hyperbolic manifold $M$. In particular, the projection map $\mathbb{H}^n\to M$ is a local isometry, but there is no local isometry $M\to \mathbb{H}^n$, for there is not even a local diffeomorphism $M\to\mathbb{H}^n$ (choose a reference point $r\in\mathbb{H}^n$ and consider $df$ at a point $p\in M$ where $d(f(p),r)$ is maximized).
(This argument works for any closed complete Riemannian manifold with infinite-diameter universal cover.)
If one defines "$M$ and $N$ are locally isometric if for any $m\in M$ there exists an $n\in N$ and neighborhoods $U_p\ni p$, $U_q\ni q$ such that $U_p$ is isometric to $U_q$", then the relation is also not symmetric. Daniel Fischer provides a counterexample in the comments.
Solution 2:
The Answer to this question is according to the following definition of "locally isometric Riemannian manifolds":
DEFFINITION: Let $M$ and $N$ be Riemannian manifolds. A differentiable mapping $$f:M\rightarrow N $$ is a "local isometry" at $p\in M$ if there is a neighborhood $U\subset M$ of $p$ such that $$f:U\rightarrow f(U) $$ is a diffeomorphism satisfying $$\langle u,v\rangle_{p}=\langle d{f}_{p}(u),d{f}_{p}(v)\rangle_{f(p)}$$
Now a Riemannian manifold $M$ is "locally isometric" to a Riemannian manifold $N$ if for every $p$ in $M$ there exists a neighborhood $U$ of $p$ in $M$ and a local isometry $$f:U \rightarrow f(U)\subset N$$
It is possible to see that the natural projection $$\pi :S^{2}\rightarrow P^{2}(\mathbb{R})$$ is a local isometry. In fact with the aid of this map along with different "suitable neighborhoods" one can say that $S^{2}$ is locally isometric to $P^{2}(\mathbb{R})$.
Now assume that the "locally isometric" is a symmetric relation. Then one would have $P^{2}(\mathbb{R})$ locally isometric to $S^{2}$. Consequently, one gets $P^2\mathbb{R}$ locally diffeomorphic to $S^2$.
But this makes a contradiction:
$S^{2}$ is an orientable manifold and hence due to the existence of the local diffeomorphisms, $P^{2}(\mathbb{R})$ should be an orientable manifold which is a contradiction (Since $P^{2}(\mathbb{R})$ is not orientable).