A Binomial Coefficient Sum: $\sum_{m = 0}^{n} (-1)^{n-m} \binom{n}{m} \binom{m-1}{l}$

This is a special case of the identity $$\sum_k \binom{l}{m+k} \binom{s+k}{n} (-1)^k = (-1)^{l+m} \binom{s-m}{n-l},$$ which is identity 5.24 on p. 169 of Concrete Mathematics, 2nd edition. With $l = n$, $m = 0$, $s = -1$, $k = m$, and $n = l$, we see that the OP's sum is $$(-1)^{2n} \binom{-1}{l-n} = \binom{-1}{l-n}.$$ This is $(-1)^{l-n}$ when $l \geq n$ and $0$ when $l < n$, as in Fabian's comment to Plop's answer.

$$\sum_{m=0}^n (-1)^{n-m} \binom{n}{m} \binom{m-1}{l} = (-1)^{l+n} + \sum_{l+1 \leq m \leq n} (-1)^{n-m} \binom{n}{m} \binom{m-1}{l}$$ So we need to compute this last sum. It is clearly zero if $l \geq n$, so we assume $l < n$.

It is equal to $f(1)$ where $f(x)= \sum_{l+1 \leq m \leq n} (-1)^{n-m} \binom{n}{m} \binom{m-1}{l} x^{m-1-l}$. We have that $$\begin{eqnarray*} f(x) & = & \frac{1}{l!} \frac{d^l}{dx^l} \left( \sum_{l+1 \leq m \leq n} (-1)^{n-m} \binom{n}{m} x^{m-1} \right) \\ & = & \frac{1}{l!} \frac{d^l}{dx^l} \left( \frac{(-1)^{n+1}}{x} + \sum_{0 \leq m \leq n} (-1)^{n+1} \binom{n}{m} (-x)^{m-1} \right) \\ & = & \frac{1}{l!} \frac{d^l}{dx^l} \left( \frac{(-1)^{n+1}}{x} + \frac{(x-1)^n}{x} \right) \\ & = & \frac{(-1)^{n+1+l}}{x^{l+1}} + \frac{1}{l!} \sum_{k=0}^l \binom{l}{k} n(n-1) \ldots (n-k+1) (x-1)^{n-k} \frac{(-1)^{l-k} (l-k)!}{x^{1+l-k}} \end{eqnarray*}$$ (this last transformation thanks to Leibniz) and since $n>l$, $f(1)=(-1)^{l+n+1}$.

In the end, your sum is equal to $(-1)^{l+n}$ if $l \geq n$, $0$ otherwise.

$\newcommand{\angles}[1]{\left\langle\, #1 \,\right\rangle} \newcommand{\braces}[1]{\left\lbrace\, #1 \,\right\rbrace} \newcommand{\bracks}[1]{\left\lbrack\, #1 \,\right\rbrack} \newcommand{\ceil}[1]{\,\left\lceil\, #1 \,\right\rceil\,} \newcommand{\dd}{{\rm d}} \newcommand{\ds}[1]{\displaystyle{#1}} \newcommand{\expo}[1]{\,{\rm e}^{#1}\,} \newcommand{\fermi}{\,{\rm f}} \newcommand{\floor}[1]{\,\left\lfloor #1 \right\rfloor\,} \newcommand{\half}{{1 \over 2}} \newcommand{\ic}{{\rm i}} \newcommand{\iff}{\Longleftrightarrow} \newcommand{\imp}{\Longrightarrow} \newcommand{\pars}[1]{\left(\, #1 \,\right)} \newcommand{\partiald}[3][]{\frac{\partial^{#1} #2}{\partial #3^{#1}}} \newcommand{\pp}{{\cal P}} \newcommand{\root}[2][]{\,\sqrt[#1]{\vphantom{\large A}\,#2\,}\,} \newcommand{\sech}{\,{\rm sech}} \newcommand{\sgn}{\,{\rm sgn}} \newcommand{\totald}[3][]{\frac{{\rm d}^{#1} #2}{{\rm d} #3^{#1}}} \newcommand{\verts}[1]{\left\vert\, #1 \,\right\vert}$ $\ds{\sum_{m = 0}^{n}\pars{-1}^{n - m}{n \choose m}{m - 1 \choose \ell}:\ {\large ?}.\qquad\ell \geq 0}$

\begin{align} &\color{#66f}{\large\sum_{m = 0}^{n}\pars{-1}^{n - m}{n \choose m} {m - 1 \choose \ell}} \\[3mm]&=\pars{-1}^{n}\sum_{m = 0}^{n}\pars{-1}^{m}{n \choose m} \oint_{0\ <\ \verts{z}\ =\ a\ <\ 1}{\pars{1 + z}^{m - 1} \over z^{\ell + 1}} \,{\dd z \over 2\pi\ic} \\[3mm]&=\pars{-1}^{n}\oint_{0\ <\ \verts{z}\ =\ a\ <\ 1} {1 \over z^{\ell + 1}\pars{1 + z}} \sum_{m = 0}^{n}{n \choose m}\pars{-z - 1}^{m}\,{\dd z \over 2\pi\ic} \\[3mm]&=\pars{-1}^{n}\oint_{0\ <\ \verts{z}\ =\ a\ <\ 1} {1 \over z^{\ell + 1}\pars{1 + z}} \bracks{1 + \pars{-z - 1}}^{n}\,{\dd z \over 2\pi\ic} \\[3mm]&=\oint_{0\ <\ \verts{z}\ =\ a\ <\ 1}{1 \over z^{\ell - n + 1}\pars{1 + z}} {\dd z \over 2\pi\ic} =\sum_{k = 0}^{\infty}\pars{-1}^{k}\oint_{0\ <\ \verts{z}\ =\ a\ <\ 1}{1 \over z^{\ell - n - k + 1}}{\dd z \over 2\pi\ic} \\[3mm]&=\sum_{k = 0}^{\infty}\pars{-1}^{k}\,\delta_{\ell - n,k} =\color{#66f}{\large\left\lbrace\begin{array}{lcl} \pars{-1}^{\ell - n} & \mbox{if} & \ell \geq n \\[2mm] 0&&\mbox{otherwise} \end{array}\right.} \end{align}