Change background color of selected text
You can edit
/usr/share/themes/Ambiance/gtk-2.0/gtkrc
/usr/share/themes/Ambiance/gtk-3.0/gtk.css
/usr/share/themes/Ambiance/gtk-3.0/settings.ini
and wherever you see selected_bg_color
change #f07746
(orange) to #0000ff
(bright blue, or whatever color you prefer)
These are system files, so to edit them you'll need to be root like so:
gksudo gedit /usr/share/themes/Ambiance/gtk-2.0/gtkrc /usr/share/themes/Ambiance/gtk-3.0/gtk.css /usr/share/themes/Ambiance/gtk-3.0/settings.ini