Type straight quotes (",') when smart quotes is turned on
I added "
and '
as replacements for something, then the replaced quotes were not converted to smart quotes in a few quick experiments. For example, setting ""
and ''
to be replaced by "
and '
respectively:
Typing ""foo"" ''bar''
resulted in "foo" 'bar'
with normal quotes. As shortcuts go, just double tapping the button instead of single tapping makes for a convenient shortcut.