Somebody who doesn't want to work but wants materials and luxury?
What would I call somebody who, like the title says, doesn't want to work but wants luxury and items/materials?
Freeload - to get or ask for things (such as food, money, or a place to live) from people without paying for them (Merriam Webster)
Such a person would be called a freeloader
Entitled
Believing oneself to be inherently deserving of privileges or special treatment. google.com
It's hard to find a word that doesn't add additional meanings. This adds the idea of thinking it's deserved.