Acyclic vs Exact

I have a question about the words "acyclic" and "exact." Why does Brown use the term "acyclic" instead of "exact" in his book Cohomology of Groups? It seems to me that these two terms exactly coincide. Are there examples(or topics in math) in which being acyclic means being sth1 and being exact means being sth2, and when restricted to the homology theory sth1 and sth2 coincide? Thank you.

Acyclic and exact are not the same. As Akhil says in his answer, the long exact for group cohomology is indeed exact, but a projective resolution of a module is acyclic because it is not exact in degree zero.

Originally, one used to say that a projective resolution $P_\bullet$ of a module $M$ was "acyclic over $M$", and that means that there is a map $\varepsilon:P_0\to M$, called an augmentation, such that if one extends the complex $P_\bullet$ so as to put $M$ in degree $-1$ with $\varepsilon$ as the last differential, then the resulting complex is exact.

Similarly, an acyclic space is not one whose singular complex is exact (there are very few such spaces!) but one whose singular complex is acyclic over $\mathbb Z$.

Mariano, you seem to be confusing a few things here. A complex is acyclic if and only if it is exact. (see for instance Exercise 1.1.5 in Weibel's Homological Algebra book, or probably anyplace where this is defined).

An object is acyclic for a functor if the derived functors of said functor vanish on the object. For instance a flasque sheaf for the global section functor.

A resolution is acyclic if the objects of the resolution are acyclic objects.

A projective resolution is acyclic for example for the $\mathrm{Hom}(\__, N)$ functor (for some $N$) because a projective module is and not because it is exact except at degree zero. That condition is encoded in the word resolution.

So, without knowing the way Brown uses this (niyazi, you'd have to be a little more specific about that) the answer to the question is something like this: as long as you are talking about a complex being acyclic, it means the same as exact, but acyclic also applies to an object, whereas we do not say that an object is exact.

Indeed, "acyclicity" of a complex means mostly the same thing as exactness (except in degree zero, as Mariano notes). I think they are just used in different contexts: people often call sequences (such as "short exact sequences" $0 \to A \to B \to C \to 0$ or also "long exact sequences" that are derived from complexes) exact, while a complex by itself is often called acyclic if it has the same property.

For instance, one would say that the long exact sequence for group cohomology is exact (probably not acyclic), but that the resolution used to compute it was acyclic (though here "exact" is probably used more often).