Is the saying "It's not that big of a deal" incorrect?

Perhaps this Ngram will answer your question.

I am aware of the weaknesses of Ngram, but it works for rough-and-ready questions like this, and shows that "big a deal" is used more than "big of a deal", at least in writing.

Even though "big a deal" is the more used, I am not sure I would say your kids are wrong in any absolute way. The 'of' is pretty much redundant, and on a personal level I see unnecessary words as a barrier to clarity, but it is used widely in some areas.