Saving local village over Google+ village
Solution 1:
Unfortunately, this is not possible. The link is done on the SuperCell servers, and there's no way to unlink an account from a Google+ (Android) or Game Center account (iOS).
You will need to create a new Google+ account to link to your village.
Just FYI, there's some information I found on Google that suggests you can unlink it by going into Google+ settings. I just tried these suggestions with a test village of mine and can co firm that process doesn't work.
Solution 2:
Yes, you can remove your old town hall from your Google account.
- Open your Android device, of course.
- Open Google Settings.
- Open Connected Apps then tap to Clash of Clans.
- Tap to Disconnect to remove this game from your account.
- Done.