Proof that ODE solutions with Wronskian identically zero are linearly dependent
Suppose that $y_1(t), \ldots, y_n(t)$ are solutions of $\frac{d^n y}{dt} + p_{n-1}(t) \frac{d^{n-1} y}{dt} + \cdots + p_1(t) \frac{dy}{dt} + p_0(t) y = 0$, and suppose that their Wronskian is zero for $t = t_0$, i.e. \begin{equation*} \left| \begin{array}{cccc} y_1(t_0) & y_2(t_0) & \cdots & y_n(t_0) \\ y_1'(t_0) & y_2'(t_0) & \cdots & y_n'(t_0) \\ \vdots & \vdots & \ddots & \vdots \\ y_1^{(n-1)}(t_0) & y_2^{(n-1)}(t_0) & \cdots & y_n^{(n-1)}(t_0) \end{array} \right| = 0. \end{equation*} Then the corresponding matrix is not invertible, and the system of equations \begin{array}{c} c_1 y_1(t_0) &+& c_2 y_2(t_0) &+& \cdots &+& c_n y_n(t_0) &=& 0 \\ c_1 y_1'(t_0) &+& c_2 y_2'(t_0) &+& \cdots &+& c_n y_n'(t_0) &=& 0 \\ \vdots &+& \vdots &+& \ddots &+& \vdots &=& 0 \\ c_1 y_1^{(n-1)}(t_0) &+& c_2 y_2^{(n-1)}(t_0) &+& \cdots &+& c_n y_n^{(n-1)}(t_0) &=& 0 \\ \end{array} has a nontrivial solution for $c_1, c_2, \ldots, c_n$ not all zero.
Let $y(t) = c_1 y_1(t) + \cdots + c_n y_n(t)$. Because $y(t)$ is a linear combination of solutions of the differential equation, $y(t)$ is also a solution of the differential equation. Additionally, because the weights satisfy the above system of equations, we have $y(t_0) = y'(t_0) = \cdots = y^{(n-1)}(t_0) = 0$.
These initial conditions and the original differential equation define an initial-value problem, of which $y(t)$ is a solution. If $p_0(t), p_1(t), \ldots, p_{n-1}(t)$ are continuous, then any initial-value problem associated with the differential equation has a unique solution. Obviously $y^*(t) = 0$ is a solution of the initial-value problem; since we know that $y(t)$ is also a solution of the same initial-value problem, it follows that $y(t) = 0$ for all $t$, not just $t = t_0$.
We now have $c_1 y_1(t) + \cdots + c_n y_n(t) = 0$ for all $t$, where $c_1, \ldots, c_n$ are not all zero. Thus the functions $y_1(t), \ldots, y_n(t)$ are linearly dependent.
Conversely, if the functions $y_1(t), \ldots, y_n(t)$ are linearly dependent, then the system of equations \begin{array}{c} c_1 y_1(t) &+& c_2 y_2(t) &+& \cdots &+& c_n y_n(t) &=& 0 \\ c_1 y_1'(t) &+& c_2 y_2'(t) &+& \cdots &+& c_n y_n'(t) &=& 0 \\ \vdots &+& \vdots &+& \ddots &+& \vdots &=& 0 \\ c_1 y_1^{(n-1)}(t) &+& c_2 y_2^{(n-1)}(t) &+& \cdots &+& c_n y_n^{(n-1)}(t) &=& 0 \\ \end{array} has a nontrivial solution for every $t$, the corresponding matrix is not invertible for any $t$, and $W[y_1, \ldots, y_n](t) = 0$.