can't swing the proof for this inequality
Let $p+p'=1$ and $q+q'=1$.
If $\log(p/q)>\log(q'/p')$ then $(p+q)\log(p/q)>(p'+q')\log(q'/p')$.
This looks deceptively simple to prove, but it's not. I couldn't crack it using Jensen's Inequality.
However, it is surely true -- although very tight. I checked it out numerically. I asked a competent colleague, who was also stumped.
It came up as I was meditating on asymmetry properties for the Kullback-Leibler divergence.
Let $x=\frac{p}{q}$ and $y=\frac{q^{\prime}}{p^{\prime}}=\frac{1-q}{1-p}.\;\;\;$ We know that $x>y$ since $\ln x>\ln y$, and
we want to show that $\color{blue}{(p+q)\ln x>(p^{\prime}+q^{\prime})\ln y}$.
Since $p=xq$ and $q^{\prime}=p^{\prime}y,\;\;$ $p+q=q(x+1)$ and $p^{\prime}+q^{\prime}=p^{\prime}(y+1)$.
Then $\displaystyle q^{\prime}=p^{\prime}y\implies 1-q=(1-p)y\implies q=1-y+py=1-y+xqy\implies q=\frac{1-y}{1-xy}$,
and $\displaystyle p^{\prime}=1-p=1-xq=1-\frac{x(1-y)}{1-xy}=\frac{1-x}{1-xy}.$
Therefore we need to show that $\displaystyle\color{blue}{ x>y\implies \frac{1-y}{1-xy}(x+1)\ln x>\frac{1-x}{1-xy}(y+1)\ln y}$.
Since $\displaystyle f(x)=\frac{(x+1)\ln x}{1-x}$ is increasing on $(0,1)$ and decreasing on $(1,\infty)$,
1) When $x<1, y<1$, we have that $\displaystyle \frac{(x+1)\ln x}{1-x}>\frac{(y+1)\ln y}{1-y}$ since $f$ is increasing on $(0,1)$,
$\;\;\;$ so it follows that $ \displaystyle\frac{1-y}{1-xy}(x+1)\ln x>\frac{1-x}{1-xy}(y+1)\ln y$.
2) When $x>1, y>1$, we have that $\displaystyle\frac{(x+1)\ln x}{1-x}<\frac{(y+1)\ln y}{1-y}$ since $f$ is decreasing on $(1,\infty)$;
$\;\;\;$ so it follows that $ \displaystyle\frac{1-y}{1-xy}(x+1)\ln x>\frac{1-x}{1-xy}(y+1)\ln y$.
(Notice that if $x>1$, then $p>q\;$ so $1-q>1-p$ and therefore $y>1$.)
Not an answer at all, but a too-long-for-comment hint to those who are trying :
The statement is equivalent to the following. For any positive numbers $a_1,a_2,b_1,b_2$ such that $a_1+a_2=1$ and $b_1+b_2=1$
$$ \log(a_1/b_1) + \log(a_2/b_2) > 0\implies (a_1+b_1) \log(a_1/b_1) + (a_2+b_2) \log(a_2/b_2) > 0$$
This assertion seems to be true, but the tempting generalization (for larger tuples, say $(a_1,a_2,a_3)$ and $(b_1,b_2,b_3)$ ) is false. This suggests that an attack via log-sum-inequality would probably not work.