Are sets constructed using only ZF measurable using ZFC?
Perhaps surprisingly, the answer to your question is no. But "morally" the answer is yes.
To see the "no" answer, there is a formula $\phi(x)$ such that a real $r$ satisfies $\phi$ iff $r$ is in the constructible universe $L$. Similarly, there is a formula defining a well-ordering $<_L$ of $L$, and therefore there is a formula $\psi$ such that $\psi(r)$ holds iff $r$ is a real in $L$, and it belongs to the $<_L$-first non-Lebesgue measurable subset of ${\mathbb R}$ in $L$. Such a set exists, since (provably in ZF) $L$ satisfies ZFC, and it is a theorem of ZFC that there are sets that are not measurable.
Now, it is consistent with ZF that $V=L$, that is, that every set is constructible. But then the set of reals defined by $\psi$ would not be measurable. This shows that one cannot prove in ZF (or ZFC) that any ZF-definable set of reals is measurable.
On the other hand, one of the most significant results in set theory is the theorem of ZFC + large cardinals that any reasonably definable set of reals is measurable; for example, any set of reals in the universe $L({\mathbb R})$, and this certainly includes all sets "naturally definable".
This first appeared in the Martin's maximum paper by Foreman, Magidor, and Shelah, where a supercompact was used, and was later refined in a paper by Woodin and Shelah, where the key notion of Woodin cardinals was isolated. [Note this is not just a consistency statement. It is a fact about the universe of sets, in the presence of sufficiently large cardinals.]
Moreover, it is consistent (but not provable) with large cardinals that any ordinal definable set of reals is measurable, carries all the usual regularity properties, etc, and in fact somewhat more. (This is usually stated nowadays in terms of determinacy.)
Our current understanding is that the "definable" or well-behaved sets of reals are the universally Baire sets. (In the presence of enough large cardinals) they are certainly measurable and in fact have all the usual regularity properties (for example, they are countable or of the same size as the reals, and they all have the property of Baire. In fact, they are determined).