As well as + verb-ing
Match the endings
A. He had been documenting a number of processes and workflows as well as liaising between the development team and its internal clients.
B. He documented a number of processes and workflows as well as liaised between the development team and its internal clients.
A is correct. Try inverting the clauses, and you can see that the sentence works equally well this way round:
'As well as liaising between the development team and its internal clients, he documented a number of processes and workflows.'
I cannot explain the grammar of this usage, but as a native English speaker and erstwhile professional sub-editor I know that A sounds idiomatic and B does not.