Where DCT does not hold but Vitali convergence theorem does
One idea that proves fruitful is to "chop up" a function that is not in $L_1[0,1]$ into pieces $f\cdot \chi_{A_k}$ where the measure of the $A_k$ are small enough to insure uniform integrability of the sequence and in such a way that the sequence converges pointwise:
Let $n$ be a positive integer and set $A_n=[2^{-(n+1)}, 2^{-n}]$. Partition $A_n$ into $n$ measurable sets $A_n^1$, $A_n^2$, $\ldots\,$, $A_n^n$ each of measure $1/(n\cdot2^{n+1})$. For $1\le i\le n$, define the function $f_n^i$ via $f_n^i(x) ={1\over x}\chi_{A_n^i}$.
Now consider the sequence $S=(f_1^1, f_2^1, f_2^2, f_3^1, f_3^2,f_3^3,f_4^1\ldots)$.
To see that this sequence is uniformly integrable:
Let $n$ be a positive integer. Set $\delta={1\over n2^{n+1}}$. Suppose $\mu(E)<\delta$. Then for any $m\ge n$ and $1\le i\le m$, we have $$ \int_E |f_m^i| \le \int_{A_m^i}|f_m^i| \le 2^{m+1}\cdot {1\over m2^{m+1}}= {1\over m}<{1\over n}. $$ While for $k<n$ and $1\le i\le k$, we have $$ \int_E |f_k^i| \le \delta\cdot 2^{k+1}={2^{k+1}\over n2^{n+1}}<{1\over n} . $$ Thus, $S$ is uniformly integrable.
By construction of the $A_n$, it is easily seen that $S$ converges pointwise to 0.
So, $S$ satisfies the hypotheses of the Vitali Convergence Theorem. But $S$ is not dominated by any $L_1$ function, since any dominating function would have to dominate $f(x)={1\over x}\notin L_1$.