Offline Installer for .NET framework 3.5, still requiring an internet connection
You need the Windows DVD or ISO. Then use:
DISM /Online /Enable-Feature /FeatureName:NetFx3 /All /LimitAccess /Source:d:\sources\sxs
Note that /Online means the working image of Windows, not an online install
A Microsoft MVP explains this process here: How to enable .NET Framework 3.5 on Windows 8 in Offline Mode