Removing healthy drives from a Storage Pool without causing data loss

  1. Under Physical drives for the storage pool you want, click/tap on the Prepare for removal link for the drive you want to remove. The drive will now be listed as Preparing for removal.
  2. Leave it until the drive is ready to be removed. This could take several hours, depending on how much data you have stored there.
  3. When the drive is listed as Ready to remove, click/tap on its Remove link.

P.S. Don't use "simple" VD in Storage Spaces, you have a big chances to lose all your data.