Increasing Google Chrome's max-connections-per-server limit to more than 6
IE is even worse with 2 connection per domain limit. But I wouldn't rely on fixing client browsers. Even if you have control over them, browsers like chrome will auto update and a future release might behave differently than you expect. I'd focus on solving the problem within your system design.
Your choices are to:
Load the images in sequence so that only 1 or 2 XHR calls are active at a time (use the success event from the previous image to check if there are more images to download and start the next request).
Use sub-domains like serverA.myphotoserver.com and serverB.myphotoserver.com. Each sub domain will have its own pool for connection limits. This means you could have 2 requests going to 5 different sub-domains if you wanted to. The downfall is that the photos will be cached according to these sub-domains. BTW, these don't need to be "mirror" domains, you can just make additional DNS pointers to the exact same website/server. This means you don't have the headache of administrating many servers, just one server with many DNS records.
I don't know that you can do it in Chrome outside of Windows -- some Googling shows that Chrome (and therefore possibly Chromium) might respond well to a certain registry hack.
However, if you're just looking for a simple solution without modifying your code base, have you considered Firefox? In the about:config you can search for "network.http.max" and there are a few values in there that are definitely worth looking at.
Also, for a device that will not be moving (i.e. it is mounted in a fixed location) you should consider not using Wi-Fi (even a Home-Plug would be a step up as far as latency / stability / dropped connections go).