Exact adjective of "conundrum"
Solution 1:
> Perplexing.
puzzling, complex, confusing, complicated, involved, hard, taxing, difficult, strange, weird, mysterious, baffling, bewildering, intricate, enigmatic, mystifying, inexplicable, thorny, paradoxical, unaccountable, knotty, labyrinthine
Solution 2:
Inscrutable is an extremely close synonym for the "difficult problem" definition.
Solution 3:
Puzzling. A conundrum is a puzzle or difficult problem, often a riddle. The word is pseudo-Latin; it was coined at Oxford in the 1590's according to OEtD. By 1790 its meaning had evolved to more or less what it is today.
Solution 4:
I'm after the "difficult problem" (but not the "pun") synonymity. It's used to describe a word from an ancient text which is seemingly not in the dictionaries; hard to find information about.
IMO, obscure, arcane or esoteric might be a better fit than "conundrous".