How to Implement *matCellDef and *ngif on the Same Cell
Solution 1:
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You can't use two structural directives on one element, so YES! you should put *ngIf on another element.
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Your styles and event listener function did't work because you have used ng-container which is not beeing created in the final result.
SOLUTION. Just put the logic into a div element
<td mat-cell *matCellDef="let r">
<ng-container *ngIf="r.Num_Of_Days !== 0;else conditionNotMet">
<div (click)="getCTData(r.Name,'Num_Of_Days','high')" class="rd">
{{r.Num_Of_Days}}
</div>
</ng-container>
</td>
OR use *ngIf on a div
<td mat-cell *matCellDef="let r">
<div *ngIf="r.Num_Of_Days !== 0;else conditionNotMet" (click)="getCTData(r.Name,'Num_Of_Days','high')" class="rd">
{{r.Num_Of_Days}}
</div>
</td>