Is there a quick proof as to why the vector space of $\mathbb{R}$ over $\mathbb{Q}$ is infinite-dimensional?

The cardinality argument mentioned by Arturo is probably the simplest. Here is an alternative: an explicit example of an infinite $\, \mathbb Q$-independent set of reals. Consider the set consisting of the logs of all primes $\, p_i.\,$ If $ \, c_1 \log p_1 +\,\cdots\, + c_n\log p_n =\, 0,\ c_i\in\mathbb Q,\,$ multiplying by a common denominator we can assume that all $\ c_i \in \mathbb Z\,$ so, exponentiating, we obtain $\, p_1^{\large c_1}\cdots p_n^{\large c_n}\! = 1\,\Rightarrow\ c_i = 0\,$ for all $\,i,\,$ by the uniqueness of prime factorizations.

As Steve D. noted, a finite dimensional vector space over a countable field is necessarily countable: if $v_1,\ldots,v_n$ is a basis, then every vector in $V$ can be written uniquely as $\alpha_1 v_1+\cdots+\alpha_n v_n$ for some scalars $\alpha_1,\ldots,\alpha_n\in F$, so the cardinality of the set of all vectors is exactly $|F|^n$. If $F$ is countable, then this is countable. Since $\mathbb{R}$ is uncountable and $\mathbb{Q}$ is countable, $\mathbb{R}$ cannot be finite dimensional over $\mathbb{Q}$. (Whether it has a basis or not depends on your set theory).

Your further question in the comments, whether a vector space over $\mathbb{Q}$ is finite dimensional if and only if the set of vectors is countable, has a negative answer. If the vector space is finite dimensional, then it is a countable set; but there are infinite-dimensional vector spaces over $\mathbb{Q}$ that are countable as sets. The simplest example is $\mathbb{Q}[x]$, the vector space of all polynomials with coefficients in $\mathbb{Q}$, which is a countable set, and has dimension $\aleph_0$, with basis $\{1,x,x^2,\ldots,x^n,\ldots\}$.

Added: Of course, if $V$ is a vector space over $\mathbb{Q}$, then it has countable dimension (finite or denumerable infinite) if and only if $V$ is countable as a set. So the counting argument in fact shows that not only is $\mathbb{R}$ infinite dimensional over $\mathbb{Q}$, but that (if you are working in an appropriate set theory) it is uncountably-dimensional over $\mathbb{Q}$.