Users still have access to Outlook Web Access after disabling account or changing password
I have changed a user's password, but it seems that he was logged in via webmail at the time, and he his session has remained alive.
I have disabled the account too at the time of active session on webmail but still the users has a active session.
Solution 1:
The web session doesn't become invalid when the account changes, unfortunately. Same thing happens if you have a user logged into a domain workstation and you disable their account. They still have a valid session on that workstation and won't notice a problem until they have to reauthenticate to that machine (logout/login or unlock), or need to access resources on another machine that they don't have a current session on.
Solution 2:
What mfinni said. One possible workaround may be to turn off the user's access to OWA via PowerShell with Set-Mailbox -Identity "user's ID" -OWAEnabled $false
. If you're using ADFS, you might be able to create an AD group which is not allowed to remotely access Office 365 and put terminated employees there.
I don't know if either will kick them out before their session expires, however, and am not in a position to test it.