Do my squad mate's outfits affect their stats?
Yes they do.
Default Alternate N7 Pack AshesDLC
EDI PD PRS n/a Shields
Javik PD PRS n/a n/a
Liara PD PRS PD PRS
Garrus Shields WD n/a WD
James Shields WD Shields WD
Ashely Shields WD PRS WD
Kaidan PRS PD WD Shields
Tali PD PRS n/a WD
All bumps are +25%, PD=Power Damage, WD=Weapon Damage, PRS=Power Recharge Speed.
Values are summarized from the wiki.