What's the difference between "C system calls" and "C library routines"?

There are multiple sections in the manpages. Two of them are:

2     Unix and C system calls
3     C Library routines for C programs

For example there is getmntinfo(3) and getfsstat(2), both look like they do the same thing. When should one use which and what is the difference?

Solution 1:

System calls are operating system functions, like on UNIX, the malloc() function is built on top of the sbrk() system call (for resizing process memory space).

Libraries are just application code that's not part of the operating system and will often be available on more than one OS. They're basically the same as function calls within your own program.

The line can be a little blurry but just view system calls as kernel-level functionality.

Solution 2:

Libraries of common functions are built on top of the system call interface, but applications are free to use both.

System calls are like authentication keys which have the access to use kernel resources.

Above image is from Advanced Linux programming and helps to understand how the user apps interact with kernel.