Is there a verb that means to inject with poison?

Those are two separate things. The verb form of poison encompasses the latter. From Merriam-Webster:

1 a : to injure or kill with poison; b : to treat, taint, or impregnate with or as if with poison

Curiously, M-W defines envenom as:

1 : to make poisonous

The freedictionary.com defines envenom as:

  1. to fill or impregnate with venom; make poisonous

Envenomate

(of a snake, spider, insect, etc.) poison by biting or stinging.

‘these observations suggest that the spiders envenomate their prey’

(Oxford Living Dictionaries)