Word for journey to mastery
Solution 1:
Apprenticeship, "a system of training a new generation of practitioners of a skill," may be appropriate.
Dues-paying also is used. Examples from link: "He spent his dues-paying years as a cocktail pianist. ... She had many years of dues-paying before her abilities were recognized."
Another relevant phrase, albeit not a single word, is honing his or her craft. Examples are easily found on the web. For example, journalnow.com writes in a headline, "Honing his craft on stage and screen: Michael Shannon is selected as RiverRun’s Emerging Master for 2011" and in the second half of the article lists Shannon's stage experience, from high school forward.
Note, for any of these terms, you might have to add "arduous" or "travail-filled" in front, or work in "seasoned veteran", if you want to indicate much hard work was involved.
Solution 2:
I described this to someone that I knew had read Malcolm Gladwell's book Outliers as someone's "Gladwell Curve". In the book, he outlines how 10,000 hours of practice are required for mastery of a subject. This is, admittedly, quite obscure.
Solution 3:
You'll find (personal) development used several times in Seven Step to Mastery. Since this also uses OP's metaphorical journey, I think it's appropriate for OP's context.