What's the word for horse-headed human? (Opposite of a centaur)
Solution 1:
That's called Ipotane.
Ipotane — Google
Ipotane:
In Greek mythology, an ipotane was a member of a race of half-horse, half-humans. The ipotanes are considered the original version of the centaur.
— Wikipedia
Or reverse-centaur (1, 2) as suggested by Greybeard
Hayagriva: Hayagriva, also spelt Hayagreeva (IAST: hayagrīva, literally 'Horse-neck'), is a horse-headed avatar of the Lord Vishnu in Hinduism.
Hayagriva — Wikipedia
Solution 2:
According to Wiki, there are these specific named gods:
Indian: https://en.wikipedia.org/wiki/Hayagriva
Chinese: https://en.wikipedia.org/wiki/Ox-Head_and_Horse-Face
The closest I saw was supposedly a half-horse/half-human 'kinnara' from Indian mythology, but it had no sources and none of the art in the main article depicts anything like this. I am disinclined to believe it to be factual.
I am not certain if a creature beyond a specific god was ever made in any mythology. As such, if you need the word in a creative project, having your created word following the etymology of any other mythical creatures that feature in the project could be one way to go about naming it.