Determine whether or not the function f it is bijective 2f(3-2x)+f(3/2-x/2)=x, where x is a real number

On the second equivalent equation you found,

$2f(y)+f(\frac{3-y}{4})=\frac{3-y}{2}$, (1)

use twice the map $x\mapsto (3-x)/2$, ie, let

$z=\frac{3-(\frac{3-y}{2})}{2}=\frac{y+3}{4}$,

$\Rightarrow y=4z-3$.

Plugging this in (1) yields

$2f(4z-3)+f(-z)=3-2z$

and by subtracting what we found from your first equation we can conclude

$f(z)=f(-z)$.

Hence $f$ is not injective, as it's an even function.