Find the minimum value of $2a+ (1/a) + (1/2b) + b$, where a, b > 0
Solution 1:
AM-GM inequality applied to $(2a,1/a,1/2b,b)$ gives
$$2a+\frac{1}{a}+\frac{1}{2b}+b \ge 4 \tag{1}$$
where equality is to be achieved for $2a=1/a=1/2b=b$. Solving this gives $a=1/\sqrt{2}$ but does not give a unique/consistent value for $b$.
Conclusion is, AM-GM cannot be applied to all four quantities at once. However, since $a,b$ are independent positive quantities, one can safely apply AM-GM separately to $(2a,1/a)$ and $(1/2b,b)$.
$$2a+\frac{1}{a}\ge 2\sqrt{2}$$ where equality is achieved for $2a=1/a \Rightarrow a=1/\sqrt{2}$. Similarly $$\frac{1}{2b}+b\ge \sqrt{2}$$ where equality is achieved for $1/2b=b \Rightarrow b=1/\sqrt{2}$.
Hence $2a+1/a + 1/2b+b$ is minimized for $a=1/\sqrt{2}$ and $b=1/\sqrt{2}$. At these values, the expression takes the value of $$2\sqrt{2}+\sqrt{2}=3\sqrt{2}$$ Indeed $3\sqrt{2}$ is larger than $4$ because our first inequation, $(1)$, still holds true.
Solution 2:
In the way you are applying AM-GM, the equality condition is not achievable. If applying AM-GM to find minimum, please be sure to check the values at which equality occurs. In this case there are no such values.
Alternatively, complete the square and rewrite it as -
$ \small \displaystyle 2a + \frac 1 a + b + \frac 1 {2b} = \left(\sqrt{2a} - \frac{1}{\sqrt a}\right)^2 + \left(\sqrt b - \frac{1}{\sqrt{2b}}\right)^2 + 3 \sqrt2$
The minimum value of the first two terms can be zero which occurs at $a = b = \frac{1}{\sqrt 2}$