Non-orientable 3-manifold has infinite fundamental group
Solution 1:
$\def\QQ{\mathbb Q}$If $\pi_1(M)$ is finite, $H_1(M;\QQ)=0$. If $M$ is non-orientable, $H_3(M;\QQ)=0$. So $\chi(M)=h_0(M;\QQ)-h_1(M;\QQ)+h_2(M;\QQ)-h_3(M;\QQ)=1+h_2(M;\QQ)>0$.
But by Poincaré duality, any odd-dimensional manifold has zero Euler characteristic.