Why define \0 as the first element of a char array in C?

Solution 1:

In your particular case this array is used as pathname for a PF_LOCAL socket; see here. And leading NUL is used to point that address is an abstract one. From man 7 unix:

an abstract socket address is distinguished by the fact that sun_path[0] is a null byte ('\0').

And this is the only reason why the first element is \0.