The meaning of 'as easy as not'

Solution 1:

It means there are two options of equal value.

In your quote, Emily pretends she could continue to ride with everybody, or walk, it is all the same to her.

I could pick up your mail for you while you're gone, as easy as not.

This means that while you're away on business, I could pick up your mail for you - or not; it's all the same to me.