How do I find out which computer is the domain controller in Windows programmatically?

With the most simple programming language: DOS batch

echo %LOGONSERVER%

In cmd on Windows, type the following commande:

nltest /dclist:{domainname}

It lists all domain controllers in particular domain

In C#/.NET 3.5 you could write a little program to do:

using (PrincipalContext context = new PrincipalContext(ContextType.Domain))
{
    string controller = context.ConnectedServer;
    Console.WriteLine( "Domain Controller:" + controller );
} 

This will list all the users in the current domain:

using (PrincipalContext context = new PrincipalContext(ContextType.Domain))
{
    using (UserPrincipal searchPrincipal = new UserPrincipal(context))
    {
       using (PrincipalSearcher searcher = new PrincipalSearcher(searchPrincipal))
       {
           foreach (UserPrincipal principal in searcher.FindAll())
           {
               Console.WriteLine( principal.SamAccountName);
           }
       }
    }
}