How do I use T-SQL's Case/When?

SELECT
   CASE 
   WHEN xyz.something = 1 THEN 'SOMETEXT'
   WHEN xyz.somethingelse = 1 THEN 'SOMEOTHERTEXT'
   WHEN xyz.somethingelseagain = 2 THEN 'SOMEOTHERTEXTGOESHERE'
   ELSE 'SOMETHING UNKNOWN'
   END AS ColumnName;

As soon as a WHEN statement is true the break is implicit.

You will have to concider which WHEN Expression is the most likely to happen. If you put that WHEN at the end of a long list of WHEN statements, your sql is likely to be slower. So put it up front as the first.

More information here: break in case statement in T-SQL

declare @n int = 7,
    @m int = 3;

select 
    case 
        when @n = 1 then
            'SOMETEXT'
    else
        case 
            when @m = 1 then
                'SOMEOTHERTEXT'
            when @m = 2 then
                'SOMEOTHERTEXTGOESHERE'
        end
    end as col1
-- n=1 => returns SOMETEXT regardless of @m
-- n=2 and m=1 => returns SOMEOTHERTEXT
-- n=2 and m=2 => returns SOMEOTHERTEXTGOESHERE
-- n=2 and m>2 => returns null (no else defined for inner case)

If logical test is against a single column then you could use something like

USE AdventureWorks2012;  
GO  
SELECT   ProductNumber, Category =  
      CASE ProductLine  
         WHEN 'R' THEN 'Road'  
         WHEN 'M' THEN 'Mountain'  
         WHEN 'T' THEN 'Touring'  
         WHEN 'S' THEN 'Other sale items'  
         ELSE 'Not for sale'  
      END,  
   Name  
FROM Production.Product  
ORDER BY ProductNumber;  
GO  

More information - https://docs.microsoft.com/en-us/sql/t-sql/language-elements/case-transact-sql?view=sql-server-2017