You can do this by making a twinx axes for the frequencies. You can switch the two y axes around so the frequencies stay on the left and the counts on the right, but without having to recalculate the counts axis (here we use tick_left() and tick_right() to move the ticks and set_label_position to move the axis labels

You can then set the ticks using the matplotlib.ticker module, specifically ticker.MultipleLocator and ticker.LinearLocator.

As for your annotations, you can get the x and y locations for all 4 corners of the bar with patch.get_bbox().get_points(). This, along with setting the horizontal and vertical alignment correctly, means you don't need to add any arbitrary offsets to the annotation location.

Finally, you need to turn the grid off for the twinned axis, to prevent grid lines showing up on top of the bars (ax2.grid(None))

Here is a working script:

import pandas as pd
import matplotlib.pyplot as plt
import numpy as np
import seaborn as sns
import matplotlib.ticker as ticker

# Some random data
dfWIM = pd.DataFrame({'AXLES': np.random.normal(8, 2, 5000).astype(int)})
ncount = len(dfWIM)

plt.figure(figsize=(12,8))
ax = sns.countplot(x="AXLES", data=dfWIM, order=[3,4,5,6,7,8,9,10,11,12])
plt.title('Distribution of Truck Configurations')
plt.xlabel('Number of Axles')

# Make twin axis
ax2=ax.twinx()

# Switch so count axis is on right, frequency on left
ax2.yaxis.tick_left()
ax.yaxis.tick_right()

# Also switch the labels over
ax.yaxis.set_label_position('right')
ax2.yaxis.set_label_position('left')

ax2.set_ylabel('Frequency [%]')

for p in ax.patches:
    x=p.get_bbox().get_points()[:,0]
    y=p.get_bbox().get_points()[1,1]
    ax.annotate('{:.1f}%'.format(100.*y/ncount), (x.mean(), y), 
            ha='center', va='bottom') # set the alignment of the text

# Use a LinearLocator to ensure the correct number of ticks
ax.yaxis.set_major_locator(ticker.LinearLocator(11))

# Fix the frequency range to 0-100
ax2.set_ylim(0,100)
ax.set_ylim(0,ncount)

# And use a MultipleLocator to ensure a tick spacing of 10
ax2.yaxis.set_major_locator(ticker.MultipleLocator(10))

# Need to turn the grid on ax2 off, otherwise the gridlines end up on top of the bars
ax2.grid(None)

plt.savefig('snscounter.pdf')

enter image description here


I got it to work using core matplotlib's bar plot. I didn't have your data obviously, but adapting it to yours should be straight forward. enter image description here

Approach

I used matplotlib's twin axis and plotted the data as bars on the second Axes object. The rest ist just some fiddeling around to get the ticks right and make annotations.

Hope this helps.

Code

import pandas as pd
import numpy as np
import matplotlib.pyplot as plt
import matplotlib
from mpl_toolkits.mplot3d import Axes3D
import seaborn as sns

tot = np.random.rand( 1 ) * 100
data = np.random.rand( 1, 12 )
data = data / sum(data,1) * tot

df = pd.DataFrame( data )
palette = sns.husl_palette(9, s=0.7 )

### Left Axis
# Plot nothing here, autmatically scales to second axis.

fig, ax1 = plt.subplots()
ax1.set_ylim( [0,100] )

# Remove grid lines.
ax1.grid( False )
# Set ticks and add percentage sign.
ax1.yaxis.set_ticks( np.arange(0,101,10) )
fmt = '%.0f%%'
yticks = matplotlib.ticker.FormatStrFormatter( fmt )
ax1.yaxis.set_major_formatter( yticks )

### Right Axis
# Plot data as bars.
x = np.arange(0,9,1)
ax2 = ax1.twinx()
rects = ax2.bar( x-0.4, np.asarray(df.loc[0,3:]), width=0.8 )

# Set ticks on x-axis and remove grid lines.
ax2.set_xlim( [-0.5,8.5] )
ax2.xaxis.set_ticks( x )
ax2.xaxis.grid( False )

# Set ticks on y-axis in 10% steps.
ax2.set_ylim( [0,tot] )
ax2.yaxis.set_ticks( np.linspace( 0, tot, 11 ) )

# Add labels and change colors.
for i,r in enumerate(rects):
    h = r.get_height()
    r.set_color( palette[ i % len(palette) ] )
    ax2.text( r.get_x() + r.get_width()/2.0, \
              h + 0.01*tot,                  \
              r'%d%%'%int(100*h/tot), ha = 'center' )

I think you can first set the y major ticks manually and then modify each label

dfWIM = pd.DataFrame({'AXLES': np.random.randint(3, 10, 1000)})
total = len(dfWIM)*1.
plt.figure(figsize=(12,8))
ax = sns.countplot(x="AXLES", data=dfWIM, order=[3,4,5,6,7,8,9,10,11,12])
plt.title('Distribution of Truck Configurations')
plt.xlabel('Number of Axles')
plt.ylabel('Frequency [%]')

for p in ax.patches:
        ax.annotate('{:.1f}%'.format(100*p.get_height()/total), (p.get_x()+0.1, p.get_height()+5))

#put 11 ticks (therefore 10 steps), from 0 to the total number of rows in the dataframe
ax.yaxis.set_ticks(np.linspace(0, total, 11))

#adjust the ticklabel to the desired format, without changing the position of the ticks. 
_ = ax.set_yticklabels(map('{:.1f}%'.format, 100*ax.yaxis.get_majorticklocs()/total))

enter image description here