Solution 1:

All you need to do is define a group with an unique ID, I have checked the implementation if group has different id's it will create a divider.

Example menu, creating the separator:

<menu xmlns:android="http://schemas.android.com/apk/res/android"
    xmlns:app="http://schemas.android.com/apk/res-auto"
    xmlns:tools="http://schemas.android.com/tools"
    tools:context=".MainActivity">

    <group android:id="@+id/grp1" android:checkableBehavior="single" >
        <item
            android:id="@+id/navigation_item_1"
            android:checked="true"
            android:icon="@drawable/ic_home"
            android:title="@string/navigation_item_1" />
    </group>

    <group android:id="@+id/grp2" android:checkableBehavior="single" >
        <item
            android:id="@+id/navigation_item_2"
            android:icon="@drawable/ic_home"
            android:title="@string/navigation_item_2" />
    </group>
</menu>

Solution 2:

create a drawable drawer_item_bg.xml like this,

    <layer-list xmlns:android="http://schemas.android.com/apk/res/android">

    <item>
        <shape android:shape="rectangle" >
            <solid android:color="#F4F4F4" />
        </shape>
    </item>

    <item android:top="-2dp" android:right="-2dp" android:left="-2dp">
        <shape>
            <solid android:color="@android:color/transparent" />
            <stroke
                android:width="1dp"
                android:color="#EAEAEA" />
        </shape>
        <!--
        android:dashGap="10px"
                android:dashWidth="10px"
                -->
    </item>

</layer-list>

and add it to NavigationView as app:itemBackground="@drawable/drawer_item_bg"

<android.support.design.widget.NavigationView
        android:id="@+id/nav_view"
        android:layout_width="wrap_content"
        android:layout_height="match_parent"
        android:background="#F4F4F4"
        android:layout_gravity="start"
        android:fitsSystemWindows="false"
        app:menu="@menu/activity_main_drawer"
        app:itemBackground="@drawable/drawer_item_bg"/>

and here we go...enter image description here