Recent progress in the irrationality measure of $\pi$
Salikhov proved the smaller bound in: "Salikhov, V. Kh. "On the Irrationality Measure of pi." Usp. Mat. Nauk 63, 163-164, 2008. English transl. in Russ. Math. Surv 63, 570-572, 2008." as referenced, e.g., on Mathworld. This appears to be the best bound in the peer-reviewed literature at the moment (as of February 2020).
Zeilberger and Zudlin have a (not-yet-peer-reviewed) arXiv preprint in which they improve Salikhov's bound to $7.1032\dots$, here.