Cannot use String.Empty as a default value for an optional parameter

Solution 1:

As of the C# 2.0 compiler, there is very little point to String.Empty anyway, and in fact in many cases it's a pessimisation, since the compiler can inline some references to "" but can't do the same with String.Empty.

In C# 1.1 it was useful to avoid creating lots of independent objects all containing the empty string, but those days are gone. "" works just fine.

Solution 2:

There's nothing to stop you from defining your own constant for the empty string if you really want to use it as an optional parameter value:

const string String_Empty = "";

public static void PrintString(string s = String_Empty)
{
    Console.WriteLine(s);
}

[As an aside, one reason to prefer String.Empty over "" in general, that hasn't been mentioned in the other answers, is that there are various Unicode characters (zero-width joiners, etc.) that are effectively invisible to the naked eye. So something that looks like "" isn't necessarily the empty string, whereas with String.Empty you know exactly what you're using. I recognise this isn't a common source of bugs, but it is possible.]