How does a language expand itself?

A computer is like an onion, it has many many layers, from the inner core of pure hardware to the outermost application layer. Each layer exposes parts of itself to the next outer layer, so that the outer layer may use some of the inner layers functionality.

In the case of e.g. Windows the operating system exposes the so-called WIN32 API for applications running on Windows. The Qt library uses that API to provide applications using Qt to its own API. You use Qt, Qt uses WIN32, WIN32 uses lower levels of the Windows operating system, and so on until it's electrical signals in the hardware.

You're right that in general, libraries cannot make anything possible that isn't already possible.

But the libraries don't have to be written in C++ in order to be usable by a C++ program. Even if they are written in C++, they may internally use other libraries not written in C++. So the fact that C++ didn't provide any way to do it doesn't prevent it from being added, so long as there is some way to do it outside of C++.

At a quite low level, some functions called by C++ (or by C) will be written in assembly, and the assembly contains the required instructions to do whatever isn't possible (or isn't easy) in C++, for example to call a system function. At that point, that system call can do anything your computer is capable of, simply because there's nothing stopping it.